Persona: Bravo Yagüe, Juan Carlos
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Bravo Yagüe
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Juan Carlos
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Publicación Detecting ultraviolet C radiation under polyethylene terephthalate (PET) packaging by thermoluminescence analysis using commercial dosimeters(Elsevier, 2024-03-07) Correcher, V.; Boronat Castaño, Cecilia; Bravo Yagüe, Juan CarlosFood irradiation is a proven technology that enhances food quality and safety by removing microorganisms and extending shelf life. Ultraviolet C radiation (UVC) has recently attracted interest due to its potential to inactivate foodborne pathogens. It relies on several advantages; however, there is limited research on its efficacy and safety particularly concerning food packaging materials such as polyethylene terephthalate (PET). This study reports on the effect of UVC radiation on commercial thermoluminescence dosimeters (namely, TLD-100, TLD-200, TLD-400 and GR-200) placed under PET films with different thicknesses (0.10, 0.42, and 0.60 mm). The results indicate the potential use of these materials for the detection of UVC radiation passing through the randomly selected PET samples. Fourier transform infrared spectroscopy assesses potential structural and chemical alterations in the PET induced by UVC exposure.Publicación Effects of UVC irradiation on polystyrene for healthcare packaging: Study by FTIR and Raman spectroscopy with thermoluminescence(Elsevier, 2024-02-14) Correcher, V.; García Guinea, Javier; Boronat Castaño, Cecilia; Bravo Yagüe, Juan CarlosThe interaction between ultraviolet C radiation (UVC) and polystyrene (PS) materials has been investigated, particularly in post-packaging irradiation processes for healthcare applications. Effective UVC penetration through PS materials, regardless of their thickness (0.16 and 0.40 mm) has been observed. However, the penetration effectiveness could be affected by the thickness of the PS material. Achieving optimal post-packaging UVC treatment requires a thorough evaluation of chemical composition and material thickness, especially in pharmaceutical and medical packaging industries. Preliminary results reveal minimal degradation in UVC-irradiated PS packaging samples, as supported by FTIR and Raman spectroscopy characterization. Minor variations could be attributed to intrinsic PS materials properties and/or their respective background, rather than the influence of UVC radiation. Consequently, PS materials exhibit resilience under the experimental conditions following UVC irradiation treatment. Furthermore, a comprehensive analysis of thermoluminescence (TL) emissions evaluates several commercial dosimeter materials for UVC radiation detection. The TLD-100 and TLD-200 dosimeters show potential as UVC detectors, displaying distinct responses linked to the non-ionizing component of UVC radiation at 310 ◦C and in the range of 150–250 ◦ C, respectively. However, the TLD-400 and GR-200 dosimeters are not suitable for UVC detection due to their spread TL emissions considering intensity and curve shape. This UVC-TL analysis consistently detects radiation in the proposed commercial dosimeter materials one-hour post-exposure, providing assurance that healthcare materials have been irradiated. Such analysis enhances reliability during extended UVC exposures, offering valuable insights for industries employing UVC-irradiated materials, particularly in healthcare applications.Publicación Effects of UVC irradiation on polystyrene for healthcare packaging: Study by FTIR and Raman spectroscopy with thermoluminescence(Elsevier, 2024-02-14) Correcher, V.; García-Guinea, J; Boronat Castaño, Cecilia; Bravo Yagüe, Juan CarlosThe interaction between ultraviolet C radiation (UVC) and polystyrene (PS) materials has been investigated, particularly in post-packaging irradiation processes for healthcare applications. Effective UVC penetration through PS materials, regardless of their thickness (0.16 and 0.40 mm) has been observed. However, the penetration effectiveness could be affected by the thickness of the PS material. Achieving optimal post-packaging UVC treatment requires a thorough evaluation of chemical composition and material thickness, especially in pharmaceutical and medical packaging industries. Preliminary results reveal minimal degradation in UVC-irradiated PS packaging samples, as supported by FTIR and Raman spectroscopy characterization. Minor variations could be attributed to intrinsic PS materials properties and/or their respective background, rather than the influence of UVC radiation. Consequently, PS materials exhibit resilience under the experimental conditions following UVC irradiation treatment. Furthermore, a comprehensive analysis of thermoluminescence (TL) emissions evaluates several commercial dosimeter materials for UVC radiation detection. The TLD-100 and TLD-200 dosimeters show potential as UVC detectors, displaying distinct responses linked to the non-ionizing component of UVC radiation at 310 ◦C and in the range of 150–250 ◦ C, respectively. However, the TLD-400 and GR-200 dosimeters are not suitable for UVC detection due to their spread TL emissions considering intensity and curve shape. This UVC-TL analysis consistently detects radiation in the proposed commercial dosimeter materials one-hour post-exposure, providing assurance that healthcare materials have been irradiated. Such analysis enhances reliability during extended UVC exposures, offering valuable insights for industries employing UVC-irradiated materials, particularly in healthcare applications.Publicación Detecting ultraviolet C radiation under polyethylene terephthalate (PET) packaging by thermoluminescence analysis using commercial dosimeters(Elsevier, 2024-03-07) Correcher, V.; Boronat Castaño, Cecilia; Bravo Yagüe, Juan CarlosFood irradiation is a proven technology that enhances food quality and safety by removing microorganisms and extending shelf life. Ultraviolet C radiation (UVC) has recently attracted interest due to its potential to inactivate foodborne pathogens. It relies on several advantages; however, there is limited research on its efficacy and safety particularly concerning food packaging materials such as polyethylene terephthalate (PET). This study reports on the effect of UVC radiation on commercial thermoluminescence dosimeters (namely, TLD-100, TLD-200, TLD-400 and GR-200) placed under PET films with different thicknesses (0.10, 0.42, and 0.60 mm). The results indicate the potential use of these materials for the detection of UVC radiation passing through the randomly selected PET samples. Fourier transform infrared spectroscopy assesses potential structural and chemical alterations in the PET induced by UVC exposure.Publicación Identification and morphological characterization of different types of plastic microparticles(Elsevier, 2024-05-15) Soliz Rojas, Dulce Lucy; Paniagua González, Gema; Muñoz Arnanz, Juan; Bravo Yagüe, Juan Carlos; Fernández Hernando, Pilar; Garcinuño Martínez, Rosa MªThe knowledge of the polymeric composition of microplastics (MPs) is interesting because offers useful information on the resistance, durability, and degradability of these materials, also allowing progress in the control of this contamination. However, there is currently a lack of reliable standardized methods for the identification, and characterization of the plastic microparticles. This work uses different techniques in a complementary manner for the identification, and characterization of MPs that more frequently are found in the environment. A total of 10 types of plastics were collected (polystyrene (PS), polyethylene terephthalate (PETE), polyethylene (PE), high- and low-density polyethylene (HDPE and LDPE, respectively), polyvinyl chloride (PVC), polypropylene (PP), polytetrafluoroethylene (PTFE), Polyamide (PA, Nylon 6,6) and poly-carbonate (PC)) and their chemical identification were analyzed by reflectance-attenuated infrared (FTIR-ATR). Furthermore, the samples were observed using light microscopy, and scan-ning electron microscopy (SEM). Also, staining with 12 different dyes was performed to improve the identification of microplastics. The results of this study revealed that PETE, PE, HDPE and LDPE, whose SEM images exhibited smoothness and flat uniformity of their surface, were not (or less) susceptible to adsorb staining solutions while PP, PA, PVC, and PTFE, were capable of adsorbing the dye solutions.