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Carbon-supported non-noble metal catalysts for efficient synthesis of the biofuel 2,5-dimethylfurfural from 5‑hydroxymethylfurfural in 1-butanol under mild conditions

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dc.contributor.authorMorales Vargas, Mª Virtudes
dc.contributor.authorConesa, J.M.
dc.contributor.authorGuerrero Ruiz, A.
dc.contributor.authorRodríguez Ramos, I.
dc.date.accessioned2025-04-24T08:47:36Z
dc.date.available2025-04-24T08:47:36Z
dc.date.issued2025-04-01
dc.descriptionThe registered version of this article, first published in “Catalysis Today, Volume 449, 2025", is available online at the publisher's website: Elsevier, https://doi.org/10.1016/j.chb.2020.106595 La versión registrada de este artículo, publicado por primera vez en “Catalysis Today, Volume 449, 2025", está disponible en línea en el sitio web del editor: Elsevier, https://doi.org/10.1016/j.chb.2020.106595
dc.description.abstract2,5-Dimethylfuran (DMF), which is one of the most promising liquid biofuels, has garnered significant attention due to its potential to develop the utilization of biomass energy. In this work, its synthesis through the hydrodeoxygenation reaction (HDO) of 5-hydroxymethylfurfural (HMF) has been studied on Ni catalysts supported on various metal oxides and a high surface graphite (HSAG), in a batch reactor, using 1-butanol as a solvent. At 180 °C and under 30 bar H2, the catalytic activity and the predominant reaction route were found to be strongly conditioned by the nature of the support, as well as by the presence of impurities depending on the commercial HMF feedstock employed. The HSAG support turned out to be the most suitable for the HDO of HMF leading to the formation of DMF, via rupture of the C-O bonds. Additionally, the catalytic performance of Co and Cu supported on this graphitic material was studied, being Cu the one that offers the best yields to DMF (95 %), even in the absence of external hydrogen (84 %), confirming that butanol acts as a hydrogen donor in addition of solvent.en
dc.description.versionversión publicada
dc.identifier.citationM.V. Morales, J.M. Conesa, A. Guerrero-Ruiz, I. Rodríguez-Ramos, Carbon-supported non-noble metal catalysts for efficient synthesis of the biofuel 2,5-dimethylfurfural from 5‑hydroxymethylfurfural in 1-butanol under mild conditions, Catalysis Today, Volume 449, 2025, 115189, ISSN 0920-5861, https://doi.org/10.1016/j.cattod.2025.115189
dc.identifier.doihttps://doi.org/10.1016/j.cattod.2025.115189
dc.identifier.issn0920-5861 | eISSN 1873-4308
dc.identifier.urihttps://hdl.handle.net/20.500.14468/26493
dc.journal.titleCatalysis Today
dc.journal.volume449
dc.language.isoen
dc.page.initial115189
dc.publisherELSEVIER
dc.relation.centerFacultad de Ciencias
dc.relation.departmentQuímica Inorgánica y Química Técnica
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/deed.es
dc.subject23 Química
dc.subject.keywordsbiomassen
dc.subject.keywordshydrogenolysisen
dc.subject.keywordshydrodeoxygenationen
dc.subject.keywordscatalytic transfer hydrogenationen
dc.subject.keywordscopperen
dc.subject.keywordsgraphiteen
dc.titleCarbon-supported non-noble metal catalysts for efficient synthesis of the biofuel 2,5-dimethylfurfural from 5‑hydroxymethylfurfural in 1-butanol under mild conditionsen
dc.typeartículoes
dc.typejournal articleen
dspace.entity.typePublication
person.familyNameMorales Vargas
person.givenNameMª Virtudes
relation.isAuthorOfPublication4e55f630-9a9b-4256-ab7d-37144eaec7f7
relation.isAuthorOfPublication.latestForDiscovery4e55f630-9a9b-4256-ab7d-37144eaec7f7
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